The storage of liquid missile propellants, namely Melanj (oxidizer consisting of nitric acid and nitrous oxides), Samine (mixture of equal parts of xylidine and triethylamine) and Isonite (isopropyl nitrate) in Azerbaijan is discussed in this paper. Recent storage conditions, the amounts of chemicals stored, the environmental factors and human geography at the two major storage facilities and chemical properties of the substances are combined for a preliminary risk assessment. Recommendations of necessary actions with respect to public and environmental safety are given.