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Solid state nuclear magnetic resonance (NMR) spectroscopy is a powerful and versatile technique for probing structural and dynamic properties of solid materials, and can provide detailed insights into the properties of hydrogen bonded systems. Of particular interest in this regard are solid state NMR experiments that investigate either the hydrogen atom directly involved in the hydrogen bond (employing...
Crystal engineering is the branch of supramolecular chemistry concerned with the design and synthesis of extended structures with predictable form and function. In this chapter, the use of hydrogen bonds to generate one-, two- and three-dimensional structures is discussed, with the different strategies employed compared. The review concentrates on systems in which two or more hydrogen bonds link components...
The design and synthesis of molecular containers is playing an increasing role in the selective removal and detection of species within solution. The cavities offered by such species provide the possibility of three-dimensional molecular recognition and therefore highly selective host species. Many varied approaches towards the design of container compounds have been adopted, ranging from rigid, covalently...
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