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This article introduces the concept of an interphase in epoxy composites as being an identifiable entity which in some circumstances can control composite properties. The review is divided into two major parts. The first describes the interphase from a phenomenological viewpoint as to its possible structure and composition. Examples are given which serve to illustrate the potential for inducing compositional...
Metal/epoxy structural adhesive bonding systems and coating systems possess the potential to provide strong metal-to-metal bonds, with a number of distinct advantages over conventional metal joining techniques, and to successfully protect metals from damaging environments, respectively. Exceptional strength of adhesion can be achieved by these systems under dry conditions. However, because metal/polymer...
The application of FT-IR and high resolution solid state NMR to the structural characterization of epoxies is described. Theoretical and experimental background is given and progress to date in these two fields summarized.
In this review, modern interpretations of the kinetics, thermodynamics and mechanisms of curing of epoxy oligomers with primary, secondary, and tertiary amines and their mixtures, as well as the structure of the resulting polymers are discussed. The effect of the structure of the reagents on their reactivity is analyzed. Kinetic peculiarities of the deep stages of the curing process are emphasized...
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