Coupled laminar natural convection with radiation in air-filled square enclosure heated from below and cooled from above is studied numerically for a wide variety of radiative boundary conditions at the sidewalls. A numerical model based on the finite difference method was used for the solution of mass, momentum and energy equations. The surface-to-surface method was used to calculate the radiative heat transfer. Simulations were performed for two values of the emissivities of the active and insulated walls (ɛ1=0.05 or 0.85, ɛ2=0.05 or 0.85) and Rayleigh numbers ranging from 103 to 2.3×106 . The influence of those parameters on the flow and temperature patterns and heat transfer rates are analyzed and discussed for different steady-state solutions. The existing ranges of these solutions are reported for the four different cases considered. It is founded that, for a fixed Ra, the global heat transfer across the enclosure depends only on the magnitude of the emissivity of the active walls. The oscillatory behavior, characterizing the unsteady-state solutions during the transitions from bicellular flows to the unicellular flow are observed and discussed.