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We successfully synthesized the first hemin-montmorillonite bio-conjugate with an amino acid residue to mimic natural peroxidase enzyme. Histamine was intercalated in montmorillonite by cation exchange, then a hemin molecule was loaded onto the histamine-montmorillonite with an adsorption capacity of 7.0 mg g −1 . The hemin-histamine-montmorillonite conjugate shows high peroxidase...
For the first time, an efficient, green, economical biomimetic catalyst (hemin-cetyltrimethylammonium bromide micelles) was discovered to degrade 2,4,6-trichlorophenol (TCP). The degradation experiments indicate that pH, temperature, the addition of 2-methylimidazole, and the amount of hydrogen peroxide influence the degradation process. Test of reusability revealed that CTAB micelles can protect...
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