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Studies of zinc electrode oxidation under the conditions of limited volume of alkaline electrolyte are carried out. It is shown, that at anodic polarization below 7–8 mV the zinc surface is covered by phase layer of zinc oxides and hydroxides. The last ones hinder diffusion of ions participating in electrochemical reactions. Then, formation of zincate complex [ $$\rm{Zn}(OH)\begin{array}{c}2-\\ 4\end{array}$$...
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