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The oxidation and nitridation of the eutectic Cr–Cr3Si alloys during exposures in air was investigated with focus on the detailed mechanism of the attack. Exposures in synthetic air (N2–21%O2), and nitrogen (N2–5%H2) atmospheres revealed inward diffusion of nitrogen as the key mechanism for the nitridation process which was markedly higher in nitrogen compared to that in air. Post-exposure investigations...
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