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Controlled-rate thermodesorption (CRTD) spectra are obtained by adjusting the heating rate in such a way that the rate of desorption can be constant. A quantitative analysis of the obtained spectra is presented, based on application of the statistical rate theory of interfacial transport (SRTIT) to describe both adsorption and desorption kinetics. The SRTIT approach relates the rates of adsorption...
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