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Vinyl ester-unsaturated polyester resin (VER) with adipic acid presented the lowest shrinkage and highest flexural strength among VER with CaCO3, polymer vinyl acetate (PVAc), or adipic acid after curing. The Gibbs free energy change of adipic acid/VER specimen was the highest among pure VER, CaCO3/VER, PVAc/VER, and adipic acid/VER, indicating the lowest polymerization spontaneity of adipic acid/VER...
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