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The formation of alumina particles from aluminum salts in the presence of poly(1-vinylimidazole) was investigated by quantitative 27Al NMR, potentiometry and FTIR spectra. The interaction of poly(1-vinylimidazole) with aluminum chloride and nitrate in an aqueous medium stabilizes [AlO4Al12(OH)24]7+ and less ordered polymeric particles. The addition of NaOH (NaOH: Al ≥ 2) results in water-insoluble...
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