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It is shown by IR-Fourier and UV-visible spectroscopy that two biligand complexes of different stoichiometric composition Ln·2L and 2Ln·2L (Ln = Eu; L = 4-pentyl-4′-cyanophenylpyridine) are formed in the course of low-temperature co-condensation of metal and ligand vapors on the surfaces cooled with liquid nitrogen. Quantum-chemical modeling of the equilibrium structures of the mono-and binuclear...
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