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A supramolecular adduct of gadolinium aqua nitrato complex and cucurbit[6]uril { [Gd(NO3)(H2O)7](C5H5N)@(C36H36N24O12)}(NO3)2·10H2O is obtained by slow diffusion of methanol into an aqueous solution containing gadolinium nitrate, pyridine, and cucurbit[6]uril. According to single crystal X-ray diffraction data, water molecules coordinated to metal atom make hydrogen bonds to polarized carbonyl groups...
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