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Absract A series of four diaminoalkane templated vanadium oxide polymeric frameworks, [V 2IV O8V 2V O2](C2H10N2), [V 2IV O8V 2V O2](C3H12N2), [V 4IV O10V 2V O4](C4H14N2) and [V 4IV O10V 2V O4](C5H16N2), have been successfully prepared under hydrothermal conditions. The crystal structures are fully characterized revealing layered structures composed of common inorganic building units, namely...
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