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The new host compounds 2 and 3 containing a biphenyl or terphenyl moiety attached to the 1-position of a bulky 2,3,4,5-tetraphenylcyclopentadiene-1-ol building unit have been synthesized. Crystal structures of corresponding inclusion complexes with n-hexane (2a), DMSO (2b) and THF (3a) are reported and comparatively discussed involving known inclusion structures of 1, being the parent of this particular...
The V-shaped racemic compound 4,12-dinitro-6,7,14,15-tetrahydro-6,14-methanocycloocta[1,2-b:5,6-b′]diquinoline 2 crystallises from solvents of differing water content as a centrosymmetric spheroidal hexamer in the form of a series of isostructural clusters (2)6·(water)x X-ray structures of these crystals in space group $$ R\bar{3} $$ show that they can exhibit an extent of hydration anywhere...
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