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Heat capacities of anhydrous α-and γ-cyclodextrin were measured by adiabaticcalorimetry between 10 K and 300 K. The thermalbehaviour of the two compounds exhibits significantdifferences. α-Cyclodextrin shows an anomalousexcess heat capacity in the entire region between 70 Kand 210 K. In the case of γ-cyclodextrin, anendothermic effect is observed at 240K. This effect isanalysed through the study of...
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