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Methyl jasmonate and jasmonate isomers were resolved for studies in stereoselectivity of biological action. Chemical modifications included fluorination at the chiral C7 carbon, trifluorination at the C12 of the pentenyl sidechain, shortening of this pentenyl to a butenyl moiety, and synthesis of the (+) and (–)-epi-methyl jasmonates. The effects of these modifications and stereospecificity were monitored...
Both abscisic acid (ABA) and jasmonates are known to promote leaf senescence. Since ABA and jasmonates have both chemical and physiological similarities, we are interested to know whether senescence of detached rice leaves induced by methyl jasmonate (MJ) is mediated through an increase in endogenous ABA levels. In darkness, the endogenous level of ABA in detached rice leaves remained unchanged in...
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