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Adsorption microcalorimetry of non-polar argon and quadrupolar nitrogen gases was carried out at 77 K and 302 K on two chemically different faujasite type zeolites (DAY and NaX). Considering absolute quantities adsorbed, the differential enthalpies of adsorption at zero coverage obtained with each system do not vary with temperature. Similarities in the differential enthalpies with increasing coverage...
The equilibrium distribution and the concentration dependence of the local and average self-diffusion coefficients for pure fluid and binary mixture components in narrow slitlike pores were analyzed. The coefficients were calculated using the lattice gas model in the quasi-chemical approximation on the assumption of a spherical shape and approximately equal sizes of the components. For the pure adsorbate,...
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