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AbstractAmphiphilic diblock copolymers consisting of a hydrophobic polystyrene block (PS) and a hydrophilic poly(ethylene oxide) block (PEO) with block sizes of 1000 or 3000g/mol for both blocks were studied at the air/water and toluene/water interface. Measurements of the film pressure of spread monolayers at the water surface reveal two limiting regimes of the am isotherms, in which the mean molecular...
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