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The crystal structure of 2-methylpyridinium tetrachloroferrate(III) was determined. The iron cation is tetracoordinated by chloride anions, and it adopts a slightly distorted tetrahedral coordination with three angles smaller, two almost equal and one larger than the tetrahedral. The compound is isostructural with its 3-, and 4-methylpyridinium analogues. The thermal properties of 2-, 3- and 4-methylpyridinium...
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