This paper presents a comparative study of the influence of different aggregated electrical circuit battery models in the sizing process of a hybrid energy storage system (ESS), composed by Li-ion batteries and supercapacitors (SCs). The aim is to find the number of cells required to propel a certain vehicle over a predefined driving cycle. During this process, three battery models will be considered. The first consists in a linear static zeroeth order battery model over a restricted operating window. The second is a non-linear static model, while the third takes into account first- order dynamics of the battery. Simulation results demonstrate that the adoption of a more accurate battery model in the sizing of hybrid ESS's prevents over-sizing, leading to a reduction in the number of cells of up to 29%, and a cost decrease of up to 10%.