A new low voltage charge pump is developed to help start up a step-up converter in energy harvesting applications. The proposed charge pump is the first to utilize both backward control scheme and two branches of charge transfer switches (CTSs) to direct charge flow. The backward control scheme uses the internal boosted voltage to dynamically control the CTSs' gate, and the two branches utilize both NMOS and PMOS to implement their switching structure. The combination of backward control scheme and two-branch operation allows the CTSs to be completely turned on and off. Thus, the reverse charge sharing phenomenon and switching loss are significantly reduced, which effectively improves pumping efficiency. The last stage is specially designed to improve the charge pump's charge and capacitance drivability. Using subthreshold operation and body-bias technique, the charge pump and its clock generator can operate under a low voltage supply. The proposed charge pump circuit is designed in a standard 0.18 m CMOS process. It consists of 6 stages, each with a 24 pF pumping capacitor (total 288 pF pumping capacitance area). Under a 320 mV supply, the measured output voltage of the proposed charge pump can rise from 0 to 2.04 V within 0.1 milliseconds.