In this paper, we propose the tree-structured expectation propagation (TEP) algorithm for low-density parity-check (LDPC) decoding over the additive white Gaussian noise (AWGN) channel. By imposing a tree-like approximation over the graphical model of the code, this algorithm introduces pairwise marginal constraints over pairs of variables, which provide joint information of the variables related. Thanks to this, the proposed TEP decoder improves the performance of the standard belief propagation (BP) solution. An efficient way of constructing the tree-like structure is also described. The simulation results illustrate the TEP decoder gain in the finite-length regime, compared to the standard BP solution. For code lengths shorter than n = 512, the gain in the waterfall region achieves up to 0.25 dB. We also notice a remarkable reduction of the error floor.