Compensation system is not only the core compenent in the human resources management and development, but also the important means for talent incentive in enterprises. The compensation structure as the part of compensation system is the important content of the compensation system designing. Recognizing its importance, this paper meticulously discusses the post, performance, ability and market-oriented compensation structure. The connotation, behavior orientation, advantages and disadvantages of compensation structure are analyzed, and thereby proposing its application in business.