Analysis of multidimensional structures is important to model verification in software engineering. An efficient extension of traditional Earleypsilas algorithm was made for a two-dimensional relation structures. The parsing table was extended first so as to record two-dimensional information of symbols and relationships and to distinguish the analyzed part from un-analyzed part in an unordered set. Then the construction process of the parsing table was reformed to realize unordered parsing for two-dimensional structures. Furthermore, based on the above approaches, the predictive mechanism of looking ahead a symbol and its relationship was introduced to reduce the redundant states during the parsing process. Finally, empirical results show that the algorithm is efficient.