We propose a method to improve Al thin film in the chemical vapor deposition (CVD) using superior Al precursor, Aluminum borohydride trimethylamine (AlBT). The deposition conditions of AlBT, which can improve factors such as sheet resistance (Rs) and reflective index (R.I.) that are related with the morphology of the CVD-Al film are optimized. The CVD-Al film by this AlBT improves via profiles and via resistance properties. Superior Al precursor, AlBT, show low particle distribution owing to its thermal-stable chemical property. These effects have AlBT to be an excellent promising precursor of CVD-Al technology to metallization process of sub 80 nm device and to be strongly production-worthy in mass production system.