We present an importance sampling method for the evaluation of the low frame error rate (FER) performance of LDPC codes under iterative decoding. It relies on a combinatorial characterization of absorbing sets, which are the dominant cause of decoder failure in the low FER region. The biased density in the importance sampling scheme is a mean-shifted version of the original Gaussian density, which is suitably centered between a codeword and a dominant absorbing set. This choice of biased density yields an unbiased estimator for the FER with a variance lower by several orders of magnitude than the standard Monte Carlo estimator. Using this importance sampling scheme in software, we obtain good agreement with the experimental results obtained from a fast hardware emulator of the decoder.