Quinhydrone/methanol treatment for the measurement of carrier lifetime in crystalline silicon substrates has been investigated. To estimate the surface passivation effect, the lifetimes of the silicon substrates were measured using the microwave photoconductive decay method. The 0.01 mol/dm/sup 3/ quinhydrone/methanol treatment exhibited a good passivation effect, and a very low surface recombination velocity was obtained. The quinhydrone/methanol treatment can provide accurate lifetime maps of single-crystalline and polycrystalline silicon wafers since a constant lifetime value without degradation can be obtained. Therefore, the quinhydrone/methanol treatment can be used for estimating the bulk lifetime of silicon substrates.