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The UV initiated solid-state polymerization of octadecyl vinyl ether (ODVE) was explored in this article. The crystallization process and crystal structure were investigated by XRD, DSC and FTIR. The kinetic results obtained from real time FTIR showed that ODVE performed quick cationic photopolymerization in crystalline form at about 25°C and the conversion of double bond reached about 70% in 10min...
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