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Different nucleation and growth mechanisms (Volmer-Weber, Frank-van der Merwe, and Stranski-Krastanov) have been found to operate in electrocrystallization and ultra-thin film formation of metals, Me, on foreign substrates, S, where 2D UPD Me adlayers on S can act as precursors for the subsequent nucleation and growth. Modern techniques, particularly in situ STM with lateral atomic resolution, give...
We investigated the early nucleation stages of evaporated gold submonolayers on different carbon surfaces (pristine HOPG, argon-ion irradiated HOPG and amorphous carbon). Gold core-level and valence band spectra were measured by monochromatised X-ray photoelectron spectroscopy (MXPS). The Au 4f spectra for the lowest coverages (0.1Å equivalent thickness) on irradiated HOPG and amorphous carbon surprisingly...
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