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We have performed the first structural study of formate adsorbed on Cu(111). The local registry of formate has been determined using normal incidence X-ray standing wavefield absorption (NIXSW). The oxygen atoms of the formate were located in atop sites, with NIXSW measurements made using the (1̄11) planes suggesting that they could be statically displaced by up to 0.33Å, and with the formate bridging...
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