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The solvation and ionization of hydroxyl groups on Ag(110) were examined with isotope exchange experiments involving OD and 18OD and temperature programmed desorption (TPD). Water adsorption onto oxygen-covered Ag(110) gives rise to the well known α, β, γ and δ peaks in TPD. The α-state represents multilayer water, the γ state an (OH)2·H2O complex, and the δ-state OH groups. Surface solvation of OH...
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