For the trinuclear copper complex [Cu 3 (tapg)(H 2 bhea) 3 ](ClO 4 ) 3 based on the tritopic bridging ligand 2,4,6-triacetylphlorogucinol (H 3 tapg) and the capping ligand 2-[bis-(2-hydroxyethyl)amino]ethylamine (H 2 bhea) a detailed study on the magnetic and electronic properties is presented. The C3-symmetric structure of the molecular assembly is preserved in the solid state structure of the compound which crystallizes in the space group R3c with a threefold rotation axis passing through the center of the molecule. Susceptibility measurements show weak ferromagnetic interactions with a coupling constant J=1.10(4)cm-1 mediated by a spin-polarization mechanism. This is confirmed by DFT calculations according the broken symmetry approach at B3LYP/def2-TZVP level of theory. Extended characterization by ESR spectroscopy both in X- and W-band confirm an exchange-coupled system with axial symmetry with g⊥=2.0633(4), g‖=2.2303(4) and an effective axial hyperfine constant A‖,eff=64G.