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Cytochrome c 3 -viologen-ruthenium(II) triad complex, Ru-V-cyt.c 3 , was prepared and characterized by using spectroscopic techniques. Effective quenching of the photoexcited state of ruthenium complex moiety by the bound viologen was observed in Ru-V-cyt.c 3 . When the system containing Ru-V-cyt.c 3 and hydrogenase was irradiated by visible light, photoinduced hydrogen...
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