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Advanced materials for hydrogen evolution reaction are central to the area of renewable energy. Here, we developed a solvothermal synthesis of metal organic framework (MOF) nanoparticles decorated with poly (3-aminobenzoic acid) (PABA) referred as MOF-3.6wt.%-PABA and MOF–5wt.%-PABA composites. The parent material (MOF) and composites were characterized by ultraviolet visible (UV-vis) and Fourier...
The electrochemical behaviour of triphenylstibine-containing Fischer carbene complexes of Mo(0) of the type [(SbPh3)(CO)4MoC(OEt)(Ar)] with Ar=2-thienyl (1), 2-furyl (2), 2-(N-methyl)pyrrolyl (3) or 2,2'-bithienyl (4) is reported. Results are compared to the related complexes [(L,L')(CO)3MoC(OEt)(Ar)] where L,L'=CO,CO; PPh3,CO; AsPh3,CO; or dppe (1,2-bis(diphenylphosphino)ethane). Linear trends and...
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