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Hierarchical TiO2 spheres (HTS) containing needle–like nanorods and decorated with Au nanoparticles are synthesized, forming the HTS-Au microspheres. These microspheres are hybridized into TiO2 nanocrystalline film to act as a scattering body on top of a pure TiO2 nanocrystalline layer, forming a novel composite photoanode. The effects of such HTS-Au microspheres on the performance of the photoanode...
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