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The application of electrochemical techniques for corrosion studies of organic coatings on reactive metals is considered from the analytical and mechanistic standpoint. Techniques such as electrochemical impedance spectroscopy (EIS), scanning vibrating electrode and scanning Kelvinprobe (SKP) are powerful tools to better understand the fundamental processes of corrosion at defects and underneath coatings...
The processes in the potential region corresponding to transpassive dissolution of Ni-Cr alloys (10 and 20 wt.% Cr), pure Ni and Cr were studied by electrochemical techniques - ring-disk voltammetry, impedance spectroscopy and dc resistance measurements - in 1 M sulphate solutions (pH values 0 and 5). Both the electronic and the ionic conductivity of the anodic film formed on Ni and Ni-Cr alloys were...
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