Pt/Au Schottky contacts were fabricated on modulation-doped Al 0 . 2 2 GaN 0 . 7 8 /GaN heterostructures. Some different surface treatments were used before the deposition of the metal contacts to prevent the formation of the native oxide layer on the samples' surfaces. Comparing the barrier height and the ideal factor of the Schottky contacts, we found that the treatment of the boiling (NH 4 ) 2 S solution can remove the native oxide layer effectively. Detailed X-ray photoelectron spectroscopy measurements were also made to investigate the chemical reactions on the surface of samples after different treatments.