Photofission cross-section of 232 Th was measured using Bremsstrahlung radiation energy 7.4–9.2MeV with energy step of 0.3MeV by employing Lexan polycarbonate film as Solid State Nuclear Track Detectors (SSNTD). The photon intensity from the Microtron accelerator facility was estimated to be 10 10 photons/s at a distance of 15cm from the Bremsstrahlung converter using EGS-4 code (Nelson et al., 1985). Photofission cross-sections were evaluated using fission fragment angular distribution measurements. The present experimental results were compared with EMPIRE-2.19 (Herman et al., 2005) code prediction of RIPL-1 and RIPL-2 (Mamdouh et al., 2001, 1998) and a new analytical formula (Gupta and Saxena, 2005) for fission barrier.