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Designed by fragment-reassembly strategy, the reaction between glycine esters and cyclic enol ethers was achieved in the catalysis of TBPA+·/O2, yielding a series of quinoline-fused lactones and 2,3-disubstituted quinolines. This approach provided an efficient method to construct quinoline skeleton, in which two new rings and two new C–C bonds were built in one pot.
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