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The metal organic framework (MOF) UHM-3, constructed with Cu(II)-paddle wheel-type nodes and a new tetracarboxylic acid linker, 5,5′-(dimethylsilanediyl)diisophthalate, has a close-packed alignment of open Cu(II) sites which are of interest for applications in gas storage and separation. Here, we first report on the growth of oriented, homogeneous and virtually defect-free (below 1%) UHM-3 MOF thin...
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