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Short GC capillary columns were coated with micro particles of the two isoreticular pillared-layer frameworks (PLFs) [Cu2(cam)2(dabco)] and [Cu2(cam)2(bipy)] (cam2− = (+)-camphoric acid, dabco = 1,4-diazabicyclo[2.2.2]octane, bipy = 4,4′-bipyridine) by the technique of the so called “Controlled SBU Approach”. It is demonstrated that the small pore openings of [Cu2(cam)2(dabco)] enable size dependent...
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