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We have developed a novel gas-phase electrocatalytic system for the conversion of CO2 into added-value chemicals. The system is based on a high-temperature proton-exchange membrane reactor containing a Cu cathodic catalyst supported on carbon nanofibers (CNFs) and an H3PO4-doped polybenzimidazole polymer electrolyte membrane (PBI). The resulting Cu–CNFs/PBI/IrO2 membrane electrode assembly (MEA) allowed...
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