Coincidence measurements of the outgoing particles in resonant soft X-ray scattering on molecules are presented. In a simplifying picture the first method measures the photoelectron and the soft X-ray photon, whereas the second method measures the photoelectron and the Auger electron in coincidence.In the first experiment the zero-kinetic energy photoelectrons are detected in a time-of-flight electron spectrometer, and photons are collected in a large solid angle by a detector situated close to the interaction region. The spectrum of N 2 shows an adiabatic 1 s line, free from electron-electron post collision interaction effects, together with structures below the ionization limit, associated with Rydberg electron shake-off during the radiative decay. Above the ionization limit the latter process is no longer possible, resulting in a drop at threshold for the total intensity. For the O 2 molecule we find an anomalous quartet/doublet intensity ratio, which we tentatively ascribe to a resonance just below the Σ 4 Sigma; - threshold. The O 2 data also reveal an inconsistency in the literature values regarding the calibration of the X-ray photoelectron and the soft X-ray absorption energy scales.In the second experiment two cylindrical mirror analyzers are used to measure electron-electron coincidences. The interpretation of several features in the conventional Auger spectrum follows directly from the results, e.g. the decay of the pure is hole almost is entirely contained in the main structures, the additional structure and the spread-out low-energy background being associated with the decay of multiply excited states. Fine structure in the decay of the singlet coupled 1 s - 1 π u - 1 π g shake-up state is well reproduced by calculations from the literature.The methods open up new perspectives on core hole excitation-emission dynamics.