An ab initio calculation of electron transfer reactivity of Mn 2 + OH 2 /Mn 3 + OH 2 redox system, in gas and in solution, has been made in this paper. The detailed geometry optimization and the scanning of the potential energy surfaces have been carried out at UMP2 (full)/6-311+G * level. The relevant energy quantities (such as the activation energy and the binding energy) are calculated at different levels of theory (HF, MP2, MP3, MP4 and QCISD and corresponding spin-projection PUHF, PMP2 and PMP3) with the same basis set (6-311+G * ). Both all-electrons and valence electrons have been correlated in energy calculations. The electronic transmission coefficient is calculated using the ab initio potential energy surface slopes and the coupling matrix element determined from the two-state model and the Slater-type d-electron wave functions. The pair distribution function is obtained using both a classical sphere approximation scheme and a novel scheme. The relevant kinetic parameters are obtained at different ab initio levels in terms of the new model. The contact-distance dependence of these parameters and the applicability of the presented models are also discussed.