The accuracy of the UB1LYP hybrid density functional as a method of calculating the isotropic hydrogen hyperfine coupling constants, a i s o ( 1 H), of a rapidly rotating methyl functional group in a semiquinone radical is investigated for the first time. The 2-methyl-1,4-benzosemiquinone anion is chosen as the simplest case. Its geometry is optimized as the torsion angle between the semiquinone ring plane and the methyl hydrogen atoms is varied in 5 o intervals. From these extensive computations, the rotationally averaged coupling constants, <a i s o ( 1 H)> R o t , are calculated and found to be in excellent agreement with experimental data.