In the present research work, the vulnerability of silicon doped polyimide by atomic oxygen present in LEO (lower earth orbit) of space was investigated. AO-exposure of a fluence of 5.4 × 101 8 atoms cm −2 significantly changed the surface resistivity properties of polyimide which is a prime factor governing spacecraft surface charging problem. This amount of fluence affected surface morphology and eroded the surface thickness as observed by SEM (scanning electron microscopy), laser beam imaging and surface profilometer study. This much exposure also increased the oxygen and silicon content on the surface as observed by XPS (X-ray photoelectron spectroscopy) and EDX (Energy-dispersive X-ray spectroscopy) study.