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Zr57Co27Al16 and La57Co27Al16 alloys with excellent glass-forming ability (GFA) were adopted to synthesize new phase-separated bulk metallic glasses (BMGs) upon rapid solidification. (ZrxLa1−x)57Co27Al16 (x=0.2, 0.4, 0.6, and 0.8) melts separate into ZrCo-rich and La-rich liquids upon cooling due to the existence of a miscibility gap in Zr-La liquids. The intrinsic and extrinsic mechanisms for the...
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