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The use of the phenomenon of self-stratification to design polyurethane coatings having amphiphilic surfaces was explored. A novel hydrophobic siloxane polymer having orthogonal carboxylic acid groups was used to create the amphiphilic surface. The acid functional siloxane polymers were synthesized using ring opening equilibration polymerization (ROEP) of two cyclic siloxane monomers and thiol-ene...
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