In this study, heat transfer measurements for falling film evaporation were performed up to very high Prandtl numbers, from 10 to 2800. Black liquor, a residual stream from the pulping process, was used as an example of a fluid that can have very high Prandtl numbers. To overcome the problem with fouling, which can be severe for black liquor due to crystal formation at higher concentrations, a new measurement method has been successfully developed which enables reliable measurements. Viscosity was clearly the most important parameter for the heat transfer coefficient, while the specific mass flow rate had a weak and positive dependence. The results were compared with existing heat transfer correlations, but none of them were able to capture the heat transfer behavior of black liquor throughout the whole range of Prandtl numbers.