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The enthalpy of mixing of liquid Al-Mg-Zn ternary liquid alloys was determined in the temperature range between 883 and 933 K using a high temperature mixing calorimeter. An association model is used to calculate the thermodynamic mixing functions of the ternary alloys based on the thermodynamic properties of the binary bordering systems. The calculated values of the enthalpy of mixing show a good agreement with measured values within the range of experimental accuracy. The presence of additional ternary interactions or ternary associates in the liquid state could not be observed.
Max-Planck-Institut für Metallforschung, Seestr. 92D-70174 StuttgartGermany
Max-Planck-lnstitut für Metallforschung, Institut für Werkstoffwissenschaft, Institut für Metallkunde, Universität Stuttgart, Seestr. 75D-70174 StuttgartGermany
Max-Planck-lnstitut für Metallforschung, Institut für Werkstoffwissenschaft, Institut für Metallkunde, Universität Stuttgart, Seestr. 75D-70174 StuttgartGermany
Max-Planck-lnstitut für Metallforschung, Institut für Werkstoffwissenschaft, Institut für Metallkunde, Universität Stuttgart, Seestr. 75D-70174 StuttgartGermany